Concrete Dictionary

A

Acid attack

Reactions of cement paste and concrete constituents with acidic solutions which lead to paste degradation and steel corrosion. It also includes carbonation (see carbonation).

Related products: CHEM-CRETE PAVIX CCC100  •  CHEM-CRETE MCE

Additives

Materials (in liquid or powder form) that are added to fresh concrete mixture for manipulating certain properties including chemical admixtures, mineral admixture (or supplementary cementitious materials) and other materials such as enhancers.

Admixture

“A material other than water, aggregates, cementitious material, and fibre reinforcement that is used as an ingredient of a cementitious mixture to modify its freshly mixed, setting, or hardened properties and that is added to the batch before or during its mixing.” ASTM C125-15b

Air entrainment

Small microscopic, regular (e.g. spherical) air voids that are intentionally incorporated in concrete structure (for controlling the impact of freezing and thawing cycles), usually with a volume percentage in the range of 4-8%.

Related products: CHEM-CRETE MCE

Air entrainment admixtures

Chemicals (e.g. suitable surfactants) added to enhance the incorporation of small regular air voids in concrete.

Related products: CHEM-CRETE MCE

Air entrapment 1

Large irregular, macro-air voids that are unintentionally incorporated in concrete structure due to mixing and other handling factors, usually 50 μm to 1 mm (or above), with a volume percentage of up to 2%.

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Air permeability

The coefficient of permeation flow of air (and gases) through a medium (concrete) under pressure, which reflects the ease of flow of gases to pass through the medium. PAV MCE

Related products: CHEM-CRETE PAVIX CCC100  •  CHEM-CRETE MCE

Air voids

Includes entrained air and entrapped air (see each).

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Algae

A group of microorganisms that grow on concrete by the conversion of carbon dioxide from the atmosphere to organic carbon, utilizing light energy, and consuming calcium and silica from the cement paste. Their growth leads to “Microbiologically Influenced Deterioration” (MID) of the paste and reinforcing steel bars (Microbiologically Influenced Corrosion (MIC)).

Related products: CHEM-CRETE PAVIX CCC100  •  CHEM-CRETE MCE

Alkali aggregate reaction (AAR)

Chemical reactions of alkaline content of cement in either mortar or concrete with reactive mineral compounds of reactive aggregates that causes durability problems (including ACR and ASR as defined below).

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Alkali carbonate reaction (ACR)

A type of AAR, that is encountered when using aggregates, containing CaMg(CO3)2, such as dolomitic rocks, causing concrete deterioration within a time scale of 2-3 years.

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Alkali–silica reactions (ASR)

A type of AAR, that involves slow reactions of alkaline content from cement with amorphous or non-crystalline silica content (SiO2) from reactive aggregates forming an expansive gel that causes cracking/durability problems within a time scale of 10-20 years.

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American Concrete Institute (ACI)

A leading authority and non-profit technical society and standards-developing organization that issues various types of guides, specifications, classifications and other technical resources and educational programs for the concrete industry, including concrete design, construction, materials, etc.

Autogenous shrinkage

A self-induced drying shrinkage caused by the suction of water from fine gel pores and some capillary pores for the hydration of the unreacted cement leading to destructive effect from the reduction in net volume of cementitious paste due to internal stresses that cause crack development (usually encountered in concrete made with low w/c ratios).

Related products: CHEM-CRETE PAVIX CCC100  •  CHEM-CRETE MCE

B

Barrier

Sheet and/or film forming material (e.g. polymeric material) that produces an external, impermeable protection against water penetration and prevents water ingress to the concrete.

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Bio-deterioration

Destructive effects of microorganism growth on concrete surfaces which may cause durability issues and other effects such as discoloration.

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Biological degradation

Similar to bio-deterioration: Destructive effects (on concrete) from the activity of microorganism that grows on concrete and lead to discoloration and causes durability threats.

Related products: CHEM-CRETE PAVIX CCC100  •  CHEM-CRETE MCE

C

C2S

(Dicalcium silicate or 2CaO·SiO2): The second main constituent of cement 2CaO·SiO2 that hydrates with water to produce the main binding material.

C3S

(Tricalcium silicate or 3CaO·SiO2): The main constituent of cement 3CaO·SiO2 that hydrates with water to produce the main binding material.

Calcium carbonate

The main constituent of limestone (CaCO3), the powder of which is added to cement, or is generated by the reaction of carbon dioxide with calcium ions in the cement.

Calcium hydroxide (CH)

The main by-product of the cement hydration (Ca(OH)2) that is responsible for the alkalinity of the paste and is the source of calcium ions.

Calcium oxide (CaO)

Lime, formed during cement production and combined with silica to form di and tri-calcium silicates. It is also used as binding material in certain pastes.

Calcium silicate hydrate gel (C−S−H gel)

The product of cement hydration that is formed from the reactions of di and tri-calcium silicates with water and creates stable, fine colloidal, faffy, foil-like crystalline structure which clusters into a gel with binding/cementing characteristic.

Capillary absorption coefficient

The coefficient of water penetration, which reflects the ease of wicking flow of water through under no, or minimal, hydrostatic pressure, through porous structure (e.g. paste, mortar or concrete)

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Capillary blocking

The creation (e.g. precipitation) of particulate materials (e.g. crystals) within the permeable pores of cement paste in concrete.

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Capillary pores

The medium to large pores within the cement paste that form connected networks creating channels for water penetration.

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Capillary porosity

The fraction of medium to large pores within the cement paste that form connected networks creating channels for water penetration.

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Carbonation

The reaction of carbon dioxide with calcium ions in the cement precipitation non-expansive limestone (CaCO3), which is a binding and pore-filling material and altering the level of alkalinity of concrete and thus forms one of the popular acid attacks. PAV MCE

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Carbonation shrinkage

A carbonation destructive effect from the reduction in net volume of cementitious paste due to internal stresses that cause crack development and result in a loss of integrity and strength of concrete.

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Cement

Reactive hydraulic material composed of inorganic compounds that sets and hardens by chemical reaction with water and is capable of binding material of aggregate particles.

Cement hydration

The reactions of di and tri-calcium silicates (and other cement constituents) with water creating the main binding material of concrete.

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Cementitious coatings

The formation of an external, impermeable, thin “film” from cement hydration (in a mixture of cement, sand and active ingredients) for protection against water penetration and preventing or minimizing water ingress to concrete.

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Cementitious material

“An inorganic material or a mixture of inorganic materials” that sets and develops strength by chemical reaction with water by formation of hydrates and is capable of doing so under water.” (ASTM)

ChemCretex

A one-component, crystalline, capillary-waterproofing cementitious coating composed of a proprietary blend of Portland cement, graded silica sand and active ingredients that sets by reaction with water and builds pore-blocking crystals.

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Chemical shrinkage

A natural reduction in net volume of cementitious paste that occurs during hydration because the reaction products occupy less volume than originally occupied by the water and unreacted cement.

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Chemical weathering

Changes in the composition, color and/or texture of exposed material to an environment.

Chloride attack

Chloride attack is the consequence of penetrations of chloride ions and water and chemical reactions that lead to destructive effects of paste disintegration (destabilization from chloride binding to the cementitious surfaces such as C-S-H gel) and corrosion of steel bars (destructing the protective film).

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Chloride ions penetration

The transport of chloride ions through water-filled concrete capillaries by diffusion (under the effect of concentration difference) and by chloride carrying with water penetration.

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Concrete

A composite material that is formed from the hydration of “mixture of hydraulic cement, aggregates, and water, with or without admixtures, fibers, or other cementitious materials.” ACI Concrete Terminology

Concrete durability 1

“The ability of concrete to resist weathering action, chemical attack, abrasion, and other conditions of service.” ACI

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Consistency

“The relative mobility or ability to flow” (ASTM. (2003). C125215b) and it is determined by measuring slump, using the standard cone test according to ASTM C143.

Contact angle

The angle between the liquid droplet (e.g. water) and a solid surface, which is usually used to classify surfaces into levels of hydrophobicity and hydrophilicity.

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Corrosion

Surface destructive chemical attack from reactions of soluble aggressive ions (such as chlorides and acidity) with reinforcing steel bars.

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Corrosion-inhibiting admixture

Admixture that is added to concrete mixtures to reduce the rate of steel corrosion due to chemical attack from soluble aggressive ions (e.g., chloride ions) such as amine carboxylates amino ester organic emulsion, chromates, and phosphates.

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Cracking

Destructive effect on concrete when internal tensile stresses are induced (by chemical or thermal actions) which restrain the concrete structure and then cause localized rupture when the induced stresses exceed the tensile strength of concrete.

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Crystalline admixture

Admixture that is added to concrete mixtures for precipitating crystals within the concrete pores for pore-blocking and reducing water permeability.

Curing of concrete

“Action taken to maintain moisture and temperature conditions in a freshly-placed cementitious mixture to allow hydraulic cement hydration and (if applicable) pozzolanic reactions to occur so that the potential properties of the mixture may develop.” ASTM C125-15b.

D

Dampproofing

Pore-blocking or filling for reducing water permeability (and/or pore-lining for reducing capillary absorption of water).

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DCE

Dual-crystallization engineered waterproofing (sealer) which refers to Chem-Crete Pavix CCC100 topical treatment.

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De-wetting

Preventing or minimizing the spread of water on a surface (or wetting) due to water-repellency characteristics.

Densifiers

A liquid material for treating concrete surface or additions to concrete mixture for increasing the density of concrete through reactions (usually silicate-based) or filling.

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Departments of Transportation (DOT)

A government agency/authority responsible for managing transportation, coordinating transportation-related matters, planning and coordinating related transportation projects.

Dicalcium silicate

(C2S or 2CaO·SiO2): The second main constituent of cement 2CaO·SiO2 that hydrates with water creating main binding material.

Diffusion

The transport of ions or soluble molecules within a medium (e.g. concrete) from a region of high concentration to a region of low concentration which is governed by the atomic or molecular motion of the diffusing species within the medium (or sometimes the ionic mobility).

Drying shrinkage

Volume reduction (of concrete) which is induced in the cement paste when water evaporates from hardened concrete subjected to conditions of wind flow creating gradients of temperature and humidity, leading to internal stresses and concrete cracking.

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Dual crystallization waterproofing

Pore-blocking or filling for reducing water permeability through the precipitation of two types of crystals (hygroscopic and hydrophilic) within the concrete pores.

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Dual-crystallization waterproofing

Dual-crystallization engineered waterproofing which refers to Chem-Crete Pavix CCC100 topical treatment.

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Durability

“The ability to resist weathering action, chemical attack, abrasion, and other conditions of service.” ACI

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Durable concrete

Concrete structure that is capable of resisting weathering action, chemical attack, abrasion, and other conditions of service.

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E

Effective porosity

The relative volume of pores (permeable pores) that are involved in the effective flow channel in the pore structure and it composes about 20-250% of the total porosity, which is responsible for water permeation within concrete.

Efflorescence

A deposit of (white) salts on a surface (e.g. concrete) from the evaporation of water (by evaporation) when an emerged solution from with the structure is exposed to surrounding air.

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Erosion

A deterioration surface impact (on concrete) from mechanical actions (e.g. abrasion and wear) caused by surface loading of moving mechanical parts over the surface.

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Ettringite

A cement hydration product in the form of weak long crystals (C6AS3H32) that are produced from the rapid exothermic (heat-releasing) reaction of tricalcium aluminate with the gypsum and causes rapid setting of the cement without a significant contribution to cement strength.

F

Flammable

Easy to ignite.

Fly ash

A type of supplementary cementitious material (SCM) forming a cementing binder and used as a partial replacement of cement including type C (with major content of CaO e.g. 23%) and type F with high content of SiO2. “a finely divided residue that results from the combustion of ground or powdered coal and that is transported by flue gases” (ASTM C618).

Freezing and thawing cycles

A major durability problem resulting from the sequential events from changes of concrete temperature below freezing and above freezing temperature leading to volume expansion and cracking from the induced internal stresses when water freezes, then creating larger pores with a loss in mass when water melts back, leading to a reduction in mechanical characteristics.

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Frost

A thin, icy layer that forms/deposits on a solid surface (e.g. concrete) due to the phase change, “condensation”, of water vapor into minute ice crystals when the temperature drops below the freezing-point of water.

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G

Gel pores

Interlayer micropores (fine pores less than 0.5 nm) that exist within hydration layers and are enclosed in cement hydration crystals (C-S-H gel) with little impact on the mechanical properties or permeability of concrete as they are not open for permeation and do not create flow channels, but they are involved in shrinkage.

Granite

A very hard crystalline rock, consisting mainly of quartz, feldspar, and hornblendes.

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Granite aggregates

Crushed hard rock of granular structure, from granite rock, used in road and airport constructions.

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H

Hardness

The resistances of a substance to surface indentation (plastic deformation).

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Hydration

The association (e.g. reaction) of a mineral compound (e.g. a cement constituent) with water leading to cementing/binding effect.

Hydraulic cement

Cement that sets and hardens by chemical reaction with water (hydration) and is capable of doing so under water (ACI 225R)

Hydrogen bonding

Attraction between hydrogen in water molecule and an electronegative atom (such as oxygen, chlorine, or fluorine) in another compound, which prompts, for example, absorbing water in gel pores making the water non-flowable and promotes water swelling within pores.

Hydrophilic crystalline admixture

Material (usually powder) that is added to concrete mixture and then precipitate during concrete curing as crystals within concrete pores leading to pore-blocking and reducing water permeability through concrete.

Hydrophilic crystalline waterproofing 1

Pore-blocking or filling for reducing water permeability through the precipitation of water-absorbing/hydrophilic crystals within the concrete pores.

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Hydrophilicity

A characteristic of water attraction (water-loving) that promotes water swelling and capillary absorption within porous solids (e.g. concrete).

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Hydrophobic admixture

Material (usually powder) that is added to concrete mixture and then reacts at the surface of pores during concrete curing forming a molecular layer with the characteristic of water-repelling that prevents/minimizes surface wetting, water swelling or capillary absorption.

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Hydrophobic impregnation

Liquid material that is applied (e.g. sprayed) at the surface of concrete (as a sealer) and then reacts at the surface of pores forming a molecular layer within a thin surface section with the characteristic of water-repelling that prevents/minimizes surface wetting, water swelling or capillary absorption.

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Hydrophobic integral waterproofing material

Material (usually powder) that is added to concrete mixture and then reacts at the surface of pores during concrete curing forming a molecular layer with the characteristic of water-repelling that prevents/minimizes surface wetting, water swelling or capillary absorption.

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Hydrophobicity

A characteristic of air-loving behavior (water-repelling) that prevents/minimizes surface wetting, water swelling or capillary absorption within porous solids (e.g. concrete).

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Hydrostatic pressure

A uniform pressure exerted perpendicularly on a surface (e.g. concrete) by a homogenous liquid (a head of water) (drives water permeation in concrete).

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Hygroscopic crystal

Crystal that interacts with water-vapor such that its size growth with reversible adsorption of moisture at high humidity condition and release it by desorption at low humidity condition.

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Hygroscopic interaction

The reversible adsorption/ desorption of water-vapor allowing crystal growth by adsorbing moisture at high humidity condition and crystal shrink by desorption at low humidity condition.

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Hygroscopicity

A characteristic of water-vapor attraction by a solid through reversible adsorption/desorption allowing crystal growth by adsorbing moisture at high humidity condition and crystal shrinking by desorption at low humidity condition.

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I

Ice adhesion (on concrete)

The level of attachment/bonding of the build-up of ice to a surface (by physical, mechanical and chemical interactions between the ice and the solid surface) indicated by the work or the free energy required to detach the ice from a surface.

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Icephobicity

Simply, it is “ice-repelling”, which reflects the surface resistance to ice adhesion.

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Impermeable pores

Pores that are not filled with water when the concrete is submerged for a prescribed time period and they do not provide flow channels for water; their water content is usually not-free or non-flowable and is physical attached to the surface (by absorption and hydrogen bonding).

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Initial Surface Absorption Test (ISAT)

A British Standard test designed to compare the water absorption properties of concretes in situ through an equation describing water absorption through an ISAT geometry circular absorbing surface.

Integral hydrophobic waterproofing material

Material (usually powder) that is added to concrete mixture and then reacts at the surface of pores during concrete curing forming a molecular layer with the characteristic of water-repelling that prevents/minimizes surface wetting and hence water swelling or capillary absorption.

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Integral waterproofing (of concrete)

The process of redesigning the pore structure by pore-blocking or filling (e.g. by crystallization) and/or pore-lining (e.g. by hydrophobic materials) for reducing water penetration through concrete, which is usually used for additions to concrete mixtures, but can also be used for penetrating treatment.

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Interfacial transition zone (ITZ)

A thin layer (10-50 μm) of the cement paste phase adjacent to the aggregates which is weak, less dense and more porous (and more permeable) than the bulk of the paste.

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Internal waterproofing admixture

Material that is added to concrete mixture for redesigning the pore structure by pore-blocking (e.g. by crystallization) and/or pore-lining (e.g. by hydrophobic materials) for reducing water penetration through concrete.

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Ion exchange

The reversible interchange of ions between a solid and a liquid (solution) surrounding the solid, without a substantial change in structure of the solid.

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Iowa Department of Transportation (Iowa DOT)

A government agency/authority of the State of Iowa that is responsible for managing transportation, coordinating transportation-related matters, planning and coordinating related transportation projects.

Isolated pores

Pores within the C-S-H gel that cannot be filled with free water when the concrete is submerged; but contains not-free or non-flowable water that is physically attached to the surface (by adsorption and hydrogen bonding).

L

Lime

Calcium oxide, CaO; prepared by heating limestone to over 800 oC.

Limestone

Sedimentary rock containing mainly calcium carbonate CaCO3.

Limestone (1L) cement

(Type 1L cement): A blended cement made of Portland cement with a significant percentage of limestone powders inter-grinded, blended or added at the time of mixing concrete at certain percentage (e.g. 15%).

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Limestone aggregates

A granular material produced from rock deposits (contains a high content of CaCO3) that is used as coarse particles in concrete mix designs.

Liquid admixtures

Chemical solution containing active ingredients that is added to concrete mixture and then interacts with cement for manipulating certain (fresh or hardened) concrete property.

Liquid membrane

Film forming liquid-applied coatings that sets and hardens by reactions and form nonpermeable film on concrete surface with minimal or no penetration within the pores.

Lithium (compounds) admixtures

Lithium-based compounds (such as lithium nitrate, nitrite, carbonate, and hydroxide) which are added to concrete mixture for reducing/mitigating the Alkali-Silica Reactions (ASR) through lithium bearing with silicate gel converting it into non-swelling particles and increasing the stability of the reactive silica in aggregate.

M

Macropores

Large capillary pores (50 nm-0.5 μm, or up to 3 μm) which exist between C-S-H crystals and provide flow channels for water. It is also used to refer to air entrapped and air-entrained voids.

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Magnesium chloride 1

Deicing salt (MgCl2) applied over concrete pavements for reducing ice adhesion and easy removal of ice, but it leads to harmful reactions with concrete by its two ions (magnesium and chloride).

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Mass concrete

“Any volume of structural concrete in which a combination of dimensions of the member being cast, the boundary conditions, the characteristics of the concrete mixture, and the ambient conditions can lead to undesirable thermal stresses, cracking, deleterious chemical reactions, or reduction in the long-term strength as a result of elevated concrete temperature due to heat from hydration.” ACI CT-18 (The minimum length varies from 0.5 m to 2.4 m).

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MCE

Multi-crystallization (crystalline) enhancer (see above).

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Membrane

Film forming material (usually polymer-based) in the forms of semisolid sheets, polymeric liquids, dispersions, and emulsions that is applied at the concrete surface and form nonpermeable membranes with minimal or no penetration within the pores.

Microbiologically Influenced Corrosion (MIC)

Biocorrosion of steel through an electrochemical process in which the organisms (corrosion-enhancing bacteria) affect the harshness and progress of corrosion by increasing the acidity (through its bioactivity) that is required for corrosion.

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Microbiologically Influenced Deterioration (MID)

Concrete destructive effect (e.g. disintegrating cement paste) resulting from the growth of microorganisms that creates small cavities and initiates sites for cracks development.

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Mitigating ASR

Lessening or diminishing the Alkali silica reactions in concrete (e.g. using low-alkali cement or incorporating admixtures).

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Mix proportioning

Specifying types and quantities of the ingredients in the concrete mixture.

Modified concrete

Concrete that includes additives or specific functional admixture for modifying its mechanical, waterproofing and/or durability characteristics.

Mold growth

Biological activity that drives the development of size and spread of mold-microorganism on concrete and leads to discoloration and causes durability threats.

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Multi-crystallization (crystalline) enhancer

Liquid addition that is added to concrete mixture for precipitating multiple types of crystals within the concrete pores for pore-blocking (reducing porosity and water permeability) and pore lining (capillary suction and water absorption).

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O

Ordinary concrete

Concrete that is made using typical mix designs without including additives or specific functional admixture (for modifying its mechanical, waterproofing and/or durability characteristics).

Ordinary Portland cement (OPC)

The standard cement binder used in typical concrete mixes that is composed of di and tri-calcium silicates (C3S and C2S), aluminate (C3A), and aluminoferrite (C4AF), all of which react with water and develop a hardened OPC paste.

Organosilicon compounds

Compounds containing carbon–silicon bonds (e.g. silane – siliconate – siloxane) and used to modify the surfaces of pores to become hydrophobic through reaction in which an OH group (from the compound) combines with an OH group at the cementitious substrate forming a chemical bond.

Organosilicon hydrophobes

Organosilicon compounds (see above).

Over- hydrophobicity

High water repelling surface characteristic (of concrete) achieved when the static water contact angle is in the range of 120-150o.

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P

Paste

The paste is made of cement that hardens with water. Cement paste includes a hardened mixture of hydration products, bound and free water, and possibly other contents and unreacted cement.

Pavix

Dual (hygroscopic and hydrophilic) crystallization (pore blocking) and hydrophobic (pore lining) topical treatment of concrete (and cementitious surfaces) for reducing porosity and creating impermeable surface and enhancing durability.

Penetrating sealer

“A liquid that is applied to the surface of hardened concrete, is colorless, is absorbed by the concrete, leaves little or nothing visible on the surface, and either prevents or decreased the penetration of liquid or gaseous media”. CT-18 Concrete Terminology.

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Penetration depth (of a sealer)

The distance within concrete (from the surface) to which a topically applied liquid sealer reaches and modify the pores.

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Permeability reducing admixtures (PRA)

Admixtures added to concrete mixture for creating pore-blocking or filling effect (and may include pore-lining effect) for reducing water permeability.

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Permeability reducing admixtures for hydrostatic pressure (PRAH)

PRA (see above) but specially for reducing permeation flow under hydrostatic pressure (e.g. through precipitation of crystals (hygroscopic and/or hydrophilic crystals) within the concrete pores (reducing porosity and densifying).

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Permeability reducing admixtures for nonhydrostatic pressure (PRAN)

PRA (see above) with functionality for reducing capillary absorption or wicking flow (by forming a water-repellent surface) in the absence of hydrostatic pressure (the term “permeability reducing” is used by ACI 212.3R-10 but it may not be valid here).

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Permeable pores

The medium to large capillary pores within the cement paste that form connected networks creating channels for water penetration.

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Permeation flow

The flow through porous media (e.g. concrete) under a pressure difference (hydrostatic pressure).

Phase change materials (PCMs)

Materials with low melting temperature (such as paraffin, polyglycol, salt hydrates such as sodium and potassium acetates, fatty acids, and stearate compounds) that have the ability to store thermal energy during high temperature surrounding condition and release it back during low temperature condition and hence can mitigate temperature changes (in concrete and in buildings).

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Plastic shrinkage

Volume reduction (of concrete) which is induced in the cement paste due to the rapid loss of water that occurs during hot weather concrete casting leading to internal stresses and surface cracking of newly laid concrete.

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Polymer-modified cementitious coating

The formation of an external, impermeable thin “film” from cement hydration (in a mixture of cement, sand and active ingredients) which combine polymeric compounds with cementitious materials for improving the mechanical properties of coatings (e.g., strength, resilience, adhesion) (e.g. by creating networking bonding) and water resistance.

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Polymeric barrier 3

Polymer-based materials in the forms of semisolid sheets, polymeric liquids, dispersions, and emulsions that are applied at the concrete surface and form nonpermeable membranes with minimal or no penetration within the pores.

Pore lining

The formation of a molecular layer at the surfaces of concrete pores with the characteristic of water-repelling that prevents/ minimizes surface wetting and water swelling or capillary absorption.

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porosity (total versus effective)

The total volume fraction of pores. The total porosity is defined as the total volume fraction of all pores (permeable and impermeable pores). The effective porosity accounts for the connected flow channel in the pore structure and it composes about 20-250% of the total porosity.

Portland cement

Standard cement that is composed of specific reactive hydraulic material which is based mainly on calcium silicate compounds with specified range of composition that sets and hardens by chemical reaction with water and is capable of binding material of aggregate particles.

Portland limestone cement (PLC)

(Type 1L cement): A blended cement made of Portland cement with a significant percentage of limestone powders inter-grinded, blended or added at the time of mixing concrete at certain percentage (e.g. 15%).

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Powder coating 2

Similar to cementitious coating: “An inorganic material or a mixture of inorganic materials that sets and develops strength by chemical reaction with water by formation of hydrates and is capable of doing so under water.” (ASTM)

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Pozzolanic material

Powdered inorganic mineral material (e.g., fly ash), which is added to concrete mixture, also termed as supplementary cementitious material (or mineral admixture) that contributes to the properties of a cementitious mixture (through pozzolanic activity). Or, “a siliceous or siliceous and aluminous material that in itself possesses little or no cementitious value but will, in finely divided form and in the presence of water, chemically react with calcium hydroxide at ordinary temperatures to form compounds possessing cementitious properties.” ASTM C125-15b

Pozzolanic reaction

Slow chemical reaction of reactive silica content in the pozzolans with the calcium hydroxide (from cement hydration) and water producing cementitious binding material of hydrated calcium silicate (similar to C-S-H gel).

R

Relative humidity (RH)

The percentage of absolute humidity (mass of water vapor (moisture) per cubic meter volume of air) relative to a maximum humidity given the same temperature.

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S

Saturated concrete scaling

Surface failure by the break off part of the cement paste (in large concrete flakes) exposing aggregates which is associated with freezing and thawing plus the destructive effect of deicing chemicals in water. Surface scaling is categorized in ACI 201.2R as “the most common form of damage from freezing and thawing in hardened concrete.”

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Sealer

“A liquid that is applied to the surface of hardened concrete, is colorless, is absorbed by the concrete, leaves little or nothing visible on the surface, and either prevents or decreased the penetration of liquid or gaseous media” (CT-18 Concrete Terminology).

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Set-retarding admixture

Material (e.g. organic acids such as carboxylic acids) that is used as an ingredient of a cementitious mixture to increase time of setting or delaying the setting by retarding the initial reactions of cement.

Sheet membrane

Polymer-based materials in the forms of semisolid sheets (typically made of thermoplastics, vulcanized rubbers, or rubberized asphalts) that are installed onto concrete surfaces by adhesion and form nonpermeable film with minimal or no penetration within the pores.

Shrinkage

Volume reduction (of concrete) which is induced in the cement paste due to thermal and/or chemical actions leading to internal stresses and concrete cracking.

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Shrinkage-reducing admixtures (SRA)

Multipurpose durability enhancing material (e.g. glycol compounds) that is added to concrete mixture mainly for reducing volume reduction (of concrete) which is induced in the cement paste and can lead to internal stresses and concrete cracking.

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Silanes

Organosilicon compounds/hydrophobes (e.g trimethoxy silane), which react with active sites within the siliceous content of concrete forming water repelling layers at the pore surface and create hydrophobic surface characteristic.

Silica

Silicon oxide (SiO2) which exists as a main constituent in cement and mineral admixtures (supplementary cementitious materials).

Silica fume (SF)

Micro-silica (supplementary cementitious material) that is composed mainly of SiO2 (e.g. over 90%). “a very fine pozzolanic material, composed mostly of amorphous silica produced by electric arc furnaces as a by-product of the production of elemental silicon or ferro-silicon alloys” ASTM C1240.

Silicate-based compound

Material (in liquid or powder form) that is added to concrete mixture (or to cementitious coatings and mortars) or sprayed over its surface and then densifies its structure and possibly creates hydrophilic crystals within its pores.

Siliconate

Water solution of organosilicon compound/hydrophobe (e.g. sodium methyl siliconate), which react with active sites at the siliceous content of concrete to form water repelling layers at the pore surface and create hydrophobic surface characteristic.

Siloxanes

Organosilicon compounds/ hydrophobes such as oligomeric alkyl alkoxy siloxanes, composed of short chains of silanes (oligomers) (e.g. poly methyl siloxane, tetra methyl di siloxane) which react with active sites at the siliceous content of concrete to form water repelling layers at the pore surface and create hydrophobic surface characteristic (they are with larger molecular structure than silanes).

Slag

blast-furnace slag: “the non-metallic product, consisting essentially of silicates and aluminosilicates of calcium and other bases that is developed in a molten condition simultaneously with iron in a blast furnace” (ASTM Terminology C 125) (Mainly include SiO2 and CaO).

Sodium oxide

Main part of the alkaline content in Portland cement (Na2O) which contributes with additional source of alkalinity (in addition to that from calcium hydroxide from cement hydration), which drives harmful reactions such as alkali silica reactions (ASR).

Sodium silicate

The main constituent of many surface hardeners/sealers (in liquid solution) and powder admixture that is added to concrete mixture (or to cementitious coatings and mortars), which densifies its structure and possibly creates hydrophilic crystals within its pores.

Sofix

Dual (hygroscopic and hydrophilic) crystallization (pore blocking) topical treatment of concrete (and cementitious surfaces) for reducing porosity and creating impermeable surface.

Solvent-based material

Solution of organic solvent and active ingredient(s) that are used for certain functionality (e.g. concrete sealer) which usually contains volatile organic compounds (VOC) that have a high vapor pressure (low boiling point) and low water solubility; thus, they create heavy organic odours which are usually harmful to public health.

Sorptivity

Coefficient of capillary absorption of water in concrete that is proportional to the level of hydrophilicity and porosity and reflects the ease of wicking flow of water through concrete or mortars (under no hydrostatic pressure).

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Spalling

Surface failure by the break off part of the cement paste exposing aggregates.

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Sulfate attack

Deterioration of concrete from its exposure to sulfate compounds (such as sodium, potassium, calcium, and magnesium sulfates e.g. from sea water) by the chemical reactions between the sulfate ions and the constituents of the cement paste which causes destabilization of the cement paste.

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Super- hydrophobicity

Extreme water repelling surface characteristic (of concrete) achieved when the static water contact angle is over 150o.

Super-hydrophobic surfaces

Surface (of concrete) with extreme water repelling characteristic achieved when the static water contact angle is over 150o.

Superplasticizer

(Also known as high range water reducer): Chemical solution added to concrete mixture for obtaining high workability and the consistency of concrete mixture (e.g., naphthalene and polycarboxylate) and used for making high-strength concrete or to place self-compacting concrete.

Supplementary cementitious material (SCM)

“An inorganic material that contributes to the properties of a cementitious mixture through hydraulic or pozzolanic activity, or both.” ASTM C125-15b

Surface treatment (of concrete)

Topical application of a (penetrating) sealer that redesigns the pore structure within a surface section of the concrete by pore-blocking and/or pore-lining.

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Swelling 1

The absorption of water within a porous (hydrophilic) structure (e.g. concrete) by capillary absorption (under no hydrostatic pressure).

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T

Thawing (in concrete)

Change (water phase in concrete) from a solid, frozen state to a liquid filling the pores, from the increase in temperature (of the surroundings).

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Thermal conduction (through concrete)

Heat transfer though a solid medium (e.g. concrete) by adjacent molecular (vibrational) energy.

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Thermal conductivity (of concrete)

The coefficient of conduction heat transfer though a solid medium (e.g. concrete) which determines its rate according to Fourier’s law.

Thermal shrinkage

Reduction of volume (of paste in concrete) caused by the existence of an extreme temperature gradient between the outer and inner sections of concrete or within the concrete structures at the early stages of cement hydration due to the variations in the exothermic heat release.

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Tricalcium silicate

C3S or 3CaO·SiO2: The main constituent of cement 3CaO·SiO2 that hydrates with water to lead the main binding material.

U

United States Corps of Engineering CRD-C 48-92

Standard Test Method for Water Permeability of Concrete which specifies the procedure for determining the water permeability of concrete when subjected to water at a pressure of 200 psi (1.38 MPa) with the calculations based upon an application of Darcy’s law for unidirectional flow at constant head.

UV radiation

Sun radiated waves with a wide wavelength range of 100-400 nm, (which usually destroy the integrity of coatings and disintegrate some surface treatments on exterior concrete surfaces).

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V

Vaporproofing

Making a surface vapor barrier that can retard transmission of water vapor.

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Volatile organic compounds (VOC)

Organic (carbon-hydrogen-based) compounds that have a high vapor pressure (low boiling point) and low water solubility; thus, they create heavy organic odours which are usually harmful to public health.

W

Water contact angle

The angle between water liquid droplet and a solid surface, which is usually used to classify surfaces into levels of hydrophobicity and hydrophilicity.

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Water permeability 1

The coefficient of permeation flow of water through a porous medium (e.g. concrete) under hydrostatic pressure, which reflects the ease of flow of gases to pass through the medium.

Water repellent admixtures

Material that is added to concrete mixture which upon setting creates the characteristic of hydrophobicity with static water contact angle above 90o.

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Water retention 1

Maintaining moisture within the structure of fresh concrete (available for cement hydration) during concrete curing.

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Water to binder ratio (w/b ratio)

The mass ratio of binder (e.g. cement) to mixing water used in the mix design for preparing concrete and mortars which controls most of fresh and cured properties.

Water to cement ratio (w/c ratio)

The mass ratio of cement to mixing water used in the mix design for preparing concrete and mortars which controls most of fresh and cured properties.

Water to cementitious materials ratio (w/cm ratio)

The mass ratio of the total binder (cement and supplementary cementitious materials such as fly ash) to mixing water used in the mix design for preparing concrete and mortars which controls most of fresh and cured properties.

Water-associated durability problems

Destructive issues in concrete structure that reduce its “ability to resist weathering action, chemical attack, abrasion, and other conditions of service” which are caused by the penetration of water in concrete.

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Water-reducing admixture

Material (e.g. liquid solution) that is added to concrete mixture for reducing the required amount of water for certain targeted characteristics of fresh concrete (e.g. consistency and workability) and then affects various other characteristics of cured concrete.

Water-repellent cement

A cement that upon setting has the characteristic of hydrophobicity with static water contact angle above 90o.

Wettability

The ability of spreading water (molecules) over a surface (e.g. concrete) governed by intermolecular interactions between water molecules and the surface and is expressed in terms of the contact angle between the solid and the fluids (hydrophilicity)

Wetting

The spreading of water (molecules) over a surface (e.g. concrete) by the attractive interactions between the water and the surface, driven by hydrophilicity.

Workability (of fresh concrete)

“Property of freshly mixed concrete that affects the ease with which it can be mixed, placed, consolidated, and struck off.” ASTM C125 15b.

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Y

Yufix

Dual (hygroscopic and hydrophilic) crystallization (pore blocking) and hydrophobic (pore lining) topical treatment of concrete (and cementitious surfaces) for reducing porosity and creating impermeable surface.